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光解速率是体现我国大气复合污染特征的关键参数,是不同污染物相互作用的枢纽。NO2的光解速率是对流层臭氧形成关键影响因子之一。然而光解速率与气溶胶相互作用及光解速率对臭氧和二次气溶胶生成贡献的问题仍缺乏深入研究。
近日,安光所高晓明研究员团队在光声光谱同时测量大气气溶胶和二氧化氮(NO2)方面取得新进展,相关研究成果以“用于同时测量气溶胶吸收和NO2浓度的基于443nm激光二极管的差分光声光谱仪”为题在线发表于光声光谱领域知名期刊Photoacoustics上。大气气溶胶、NO2是大气主要污染物之一,气溶胶吸收的在线测量仍然是难题之一,光声光谱因其不受光散射影响、探测器不受光波段限制等特点,在测量气溶胶、痕...
Quasi-Biennial Oscillation signals can be found in the evolution of the three constituents up to at least 40 km. We found that NO3 is positively correlated with temperature up to 45 km in the region w...
Results from a regional air quality forecast model, AIRPACT-3, are compared to OMI tropospheric NO2 integrated column densities for an 18 month period over the Pacific Northwest. AIRPACT column densit...
The Global Ozone Monitoring by Occultation of Stars (GOMOS) instrument onboard the European Space Agency's ENVISAT satellite measures ozone, NO2, NO3, H2O, O2, and aerosols using the stellar occultati...
Photolysis frequencies for NO2 are modeled for the conditions in urban streets, which are taken into account as canyons with variable height and width. The effect of a street canyon is presented with ...
We present a comparison of tropospheric NO2 from OMI measurements to the median of an ensemble of Regional Air Quality (RAQ) models, and an intercomparison of the contributing RAQ models and two globa...
A new path for hydroxyl radical formation via photo-excitation of nitrogen dioxide (NO2) and the reaction of photo-excited NO2 with water is evaluated using the UCI-CIT model for the South Coast Air B...
With increasing NO2 concentration in the troposphere, the importance of NO2 reaction with mineral dust in the atmosphere needs to be evaluated. Until now, little is known about the reaction of NO2 wit...
We present a kinetic double-layer surface model (K2-SURF) that describes the degradation of polycyclic aromatic hydrocarbons (PAHs) on aerosol particles exposed to ozone, nitrogen dioxide, water vapor...
We present the first nighttime measurements of OClO from a limb-viewing satellite instrument in the Arctic polar vortex. The relationship between OClO, NO2 and O3 slant column densities in the Arctic ...
This study assesses in detail the effects of heterogeneous chemistry on the particle surface and gas-phase composition by modeling the reversible co-adsorption of O3, NO2, and H2O on soot coated with ...
The inventory of NOx emission from international shipping has been evaluated by comparing NO2 tropospheric columns derived from the satellite instruments SCIAMACHY (January 2003 to February 2008), GOM...
Corrigendum to "Satellite observations and model simulations of tropospheric NO2 columns over south-eastern Europe" published in Atmos. Chem. Phys., 9, 6119–6134, 2009.
With the increasing availability of observational data from different sources at a global level, joint analysis of these data is becoming especially attractive. For such an analysis – oftentimes with ...

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