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Abstract: Fourier transform infrared (FTIR) spectroscopy investigations in the near infrared (NIR) region of synthetic and natural kaolinites with various octahedral substitutions have been carried ou...
Abstract: Structural Fe3+ in kaolinites and dickites covering a broad range of disorder was investigated using electron paramagnetic resonance (EPR) spectroscopy at both the X and Q-band frequencies. ...
Abstract: A new technique utilizing Raman microscopy and Fourier transform infrared (FTIR) microscopy is described. This technique uses thin films of oriented clay aggregates on glass slides suitable ...
This study compared surface characteristics and dissolution behavior of well-crystallized (KGa-1b) and poorly crystallized (KGa-2) kaolinite standards. Atomic force microscopy (AFM) revealed that pa...
Abstract: Nanomorphological structure of well-crystallized Georgia and poorly crystallized North Queensland kaolinite particles have been compared using field emission scanning electron microscopy (SE...
Abstract: Hydrogen- (δD = −106 to −97‰) and oxygen-(δ18O = +14.0 to +16.6‰) isotope compositions of kaolinite from late Cretaceous and Oligocene deposits at Iwaizumi, northeastern Japan, i...
To obtain Cu-kaolinites with a controlled range of chemical compositions, syntheses were performed by hydrothermally ageing gels with kaolinite stoichiometric compositions. Gels were prepared with sod...
A new model for the description of the structural disorder in natural kaolinite materials is proposed, based on the stacking of two 1:1 layers and their enantiomorphs, and encompassing previously prop...
A new appraisal of radiation-induced defects (RID) in natural kaolinite, i.e., positive trapped holes on oxygen atoms, has been undertaken using Q-band EPR spectra, recorded at 93 K, of irradiated ann...
The substitution of Fe3+ in the kaolinite structure is studied by EPR spectrometry and by FTIR spectrometry on a large set of kaolins from different origins (sedimentary and primary ores, soil kaolins...
A suite of Georgia kaolinites, ranging from well-ordered to very poorly ordered samples, were studied to explore correlations between degree of structural disorder, geological environment, Fe3+ conten...
Several hydrates can be synthesized from well-crystallized kaolinites; of importance to the present work are a 10-Å hydrate (called the QS-10 hydrate), an 8.6-Å hydrate, and two kinds of p...
Four hydrates with d(001) = 8.4, 8.6, and 10 侌 (two types) were synthesized by intercalating kaolinite with dimethylsulfoxide and treating the intercalated clay with fluoride ions. X-ray powder diffra...
Kaolinites” from classic, large deposits of kaolin are shown commonly in scanning electron micrographs to be mixtures, at least in part, in microdimensions, of kaolin-mineral polymorphs.Artificial mi...
Until now, the different attempts to describe the defects of kaolinites were based on the ideas that (i) the hkl reflections with k = 3n are Bragg reflections, while (ii) the hkl reflections with k ≠ ...

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