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过渡金属氧化物渗透对LSM-YSZ阴极性能的影响(Transition Metal Oxide Infiltration Effect on the Performance of LSM-YSZ Cathode)
SOFC LSM-YSZ阴极 过渡金属氧化物 渗透法
2010/8/24
Transition metal (Mn, Fe, Co, Ni, Cu) oxide was formed in LSM-YSZ cathode by nitrate solution infiltration method. LSM-YSZ/YSZ/LSM-YSZ symmetric cell performance at intermediate temperature range 600~...
过渡金属掺杂Ru-Se簇合物电催化剂氧还原性能的对比研究(Comparison of Electrocatalytic O2 Reduction Performances between Transition Metal Doped Ru-Se Cluster)
氧电还原 Ru纳米簇硫族化合物 电催化剂 抗甲醇性
2010/8/24
采用羰基金属化合物低温合成法制备了不同掺杂元素的M-Ru-Se(M=Fe,W,Mo)簇合物,并应用旋转圆盘电极电位扫描法测试簇合物的电催化活性及其抗甲醇性,采用TEM、XRD、EDS技术表征催化剂的微观形貌、结构和组成。结果显示,掺杂过渡元素对簇合物的催化活性及其抗甲醇性有明显的影响,其中Mo-Ru-Se的还原电流最高,催化活性最高,W-Ru-Se次之,Fe-Ru-Se最低;电解质中加入甲醇后,W...
The Influence of Transition Metal Ions on the Kinetics of Ascorbic Acid Oxidation by Methylene Blue in Strongly Acidic Media
The Influence of Transition Metal Ions the Kinetics of Ascorbic Acid Oxidation Methylene Blue
2010/4/22
The kinetics of the oxidation of L-ascorbic acid (H2 A) by methylene blue was investigated in strongly acidic media over the temperature range 22-40 oC. The kinetic studies were carried out as a funct...