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A new method to extract quantitative information from poorly resolved Si magic-angle spinning (MAS) nuclear magnetic resonance (NMR) spectra of natural mixed-layer illite-smectite (I-S) clays29Si i...
Pyrope-grossular solid solutions, (Mg,Ca) Al Si O , of composition Py Gr and Py Gr were3 2 3 12 85 15 75 25 synthesized at 1000, 1200, and 1400 ?C and 30 kbars in a piston-cylinder device. The synt...
17Three- and five-quantum O MAS NMR experiments are used to resolve fully the three crystallo- graphically distinct oxygen species in forsterite (Mg SiO ). The chemical shift and quadrupolar pa-2 4...
A magic-angle-spinning nuclear magnetic resonance (MAS NMR) spectroscopic study was done on the series of synthetic gallian-fluor amphiboles to identify the extent of Ga and Si ordering in the Si MA...
29The SiMASNMRspectrumofarmenitefromWasenalp(Valais,Switzerland)indicates completeSi,Alordering.Thesamechemicalshifts(82.3,95.0,and101.8ppm)were alsomeasuredforarmenitefromRe!migny(Quebec,Canada),ho...
Abstract: Eight kaolinite and 2 halloysite samples were analyzed using 27Al magic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy, chemical analysis and magnetic susceptibility to und...
We report the compositional systematics of the 29 Si MAS NMR spectra of richterite,[A](Na,K,Rb)1(Na,Ca,Sr)2Mg5Si8O22 (OH,F)2; pargasite, NaCa2Mg4AlSi6Al2O2(OH)2; and fluor-edenite, NaCa2Mg5Si7AlO22F2....
Twoseriesofleucitegroupmaterials,withK,Rb,andCsasextra-frameworkcations,havebeensynthesizedbyionexchangefromanaturalwell-orderedanalciteandanatural29 27disorderedleucite.Siand AlMASNMRdatafortheanalci...
The11.7T Mg, Al, Si,and BMASNMRspectraarereportedforwell-charac-terizedgrandidierite,(Mg,Fe)AlSiBO ,whichcontainsbothAlandMgin?vefoldcoor-dinationwithoxygen.TheMgspectrumisthe?rsttobereportedfor Mg,an...
We present 29SiMAS-NMR spectroscopic data for a series of synthetic feldspar samples along the join CaAI2Si20g-SrAI2Si20g, from which the composition dependence and cou- pling of order parameters de...
The dissolved H20 concentrations of experimentally produced, Fe-free, nominally an-hydrous minerals (NAMs) have been measured using, for the first time, IH magic-angle-spinning NMR spectroscopy. Atlea...
The structural phase transitions ofmonoclinic tridymite that occur at elevated temper-atures, as wellas the structure of the high-temperature modifications, have been studied by 29SiMASNMR. The sample...
AMonteCarlo method wasdeveloped to determine the distribution ofAland Sications from 29SiMASNMR data for framework aluminosilicates. The method wasused to an-alyze data obtained from Cs-exchanged leuc...
Kaolinite-richsamples wereselectedfor 27 Aland 29SiMASNMRstudy to explore the effectofFeontheir spectraandprovide insight into the nature ofFeorderingin kaolinite. Initial characterization bychemicala...
This paper compares the results of 27Al nuclear magnetic resonance spectroscopy (NMR) and Al-K-edge X-ray Absorption Near Edge Structure (XANES) of natural imogolite and allophanes and some crystallin...

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