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Evaluation of the Energetics of the Concerted Acid-Base Mechanism in Enzymatic Catalysis:The Case of Ketosteroid Isomerase
Energetics Concerted Acid-Base Mechanism Enzymatic Catalysis Ketosteroid Isomerase
2016/5/25
Structures of enzymes invariably reveal the proximity of acidic and basic residues to reactive sites on the substrate, so it is natural and common to suggest that enzymes employ concerted mechanisms t...
Energetics of Primary Charge Separation in Bacterial Photosynthetic Reaction Center Mutants:Triplet Decay in Large Magnetic Fields
horseradish peroxidase lignin peroxidase enzymatic oxidations N-demethylation methylene blue azure B azure C
2016/5/24
The triplet state of aromatic molecules forms and decays by intersystem crossing, as originally demonstrated by Kasha and Lewis. By contrast, the triplet state of the primary electron donor, 3 P, in p...
Energetics of Initial Charge Separation in Bacterial Photosynthesis:The Triplet Decay Rate in Very High Magnetic Fields
Photosynthesis Electron transfer Reaction center Magnetic field effect primary electron acceptor primary electron donor quinone
2016/5/20
The triplet state of the primary electron donor is formed in bacterial reaction centers when electron transfer to the quinone is blocked. The relative quantum yield of formation and the rate of decay ...